The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Peroxy radicals / Alkylperoxy / CH3O2 / CoxTyndall(1980)_298K_250nm

DATAFILE: CH3O2_CoxTyndall(1980)_298K_250nm.txt
NAME: methylperoxy radical
FORMULA: CH3O2
AUTHOR(YEAR): CoxTyndall(1980)
T: 298K
λ: 250nm
BIBLIOGRAPHY: R.A. Cox and G.S. Tyndall, "Rate constants for the reactions of CH3O2 with HO2, NO and NO2 using molecular modulation spectroscopy", J. Chem. Soc. Faraday Trans. II 76, 153-163 (1980); DOI: 10.1039/F29807600153
COMMENTS: Molecular modulation spectrometry (m.m.s.) was employed to measure the rate constants for the reactions of CH3O2 with HO2, NO2, and NO; CH3O2 was generated by the modulated photolysis at 350 ± 50 nm of mixtures of Cl2 in the presence of CH4 and O2 and was measured in absorption at 250 nm

Preliminary report:

R.A. Cox and G.S. Tyndall, "Rate constants for reactions of CH3O2 in the gas phase," Chem. Phys. Lett. 65, 357-360 (1979); DOI: 10.1016/0009-2614(79)87081-5

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